Microstructural impacts on ionic conductivity of oxide solid electrolytes from a combined atomistic-mesoscale approach

Researchers develop “broad suite of multiscale simulation capabilities to help identify, assess and overcome microstructural impacts on ion transport in solid electrolytes. “


Academic paper from Lawrence Livermore National Laboratory (LLNL) scientists in collaboration with San Francisco State University and the The Pennsylvania State University.


“Although multiple oxide-based solid electrolyte materials with intrinsically high ionic conductivities have emerged, practical processing and synthesis routes introduce grain boundaries and other interfaces that can perturb primary conduction channels. To directly probe these effects, we demonstrate an efficient and general mesoscopic computational method capable of predicting effective ionic conductivity through a complex polycrystalline oxide-based solid electrolyte microstructure without relying on simplified equivalent circuit description. We parameterize the framework for Li7-xLa3Zr2O12 (LLZO) garnet solid electrolyte by combining synthetic microstructures from phase-field simulations with diffusivities from molecular dynamics simulations of ordered and disordered systems. Systematically designed simulations reveal an interdependence between atomistic and mesoscopic microstructural impacts on the effective ionic conductivity of polycrystalline LLZO, quantified by newly defined metrics that characterize the complex ionic transport mechanism. Our results provide fundamental understanding of the physical origins of the reported variability in ionic conductivities based on an extensive analysis of literature data, while simultaneously outlining practical design guidance for achieving desired ionic transport properties based on conditions for which sensitivity to microstructural features is highest. Additional implications of our results are discussed, including a possible connection between ion conduction behavior and dendrite formation.”

Find LLNL news article here and the open access technical paper here. Published December 2021.

Heo, T.W., Grieder, A., Wang, B. et al. Microstructural impacts on ionic conductivity of oxide solid electrolytes from a combined atomistic-mesoscale approach. npj Comput Mater 7, 214 (2021). https://doi.org/10.1038/s41524-021-00681-8

The multiscale model incorporates both microstructural (left) and atomistic (right) simulations to understand barriers to ion transport in solid-state battery materials. Image by Brandon Wood, Tae Wook Heo and Sabrina Wan/LLNL.

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